The oxidative coupling polymerization of 2,6-dimethylphenol catalyzed by a μ-OCH3-bridged dicopper(II) complex catalyst

被引：21

作者：

Gao, J ^{[1
]}

Zhong, SH

Zingaro, RA

机构：

[1] Tianjin Univ, Coll Chem Engn & Technol, Tianjin 300072, Peoples R China

[2] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2004年 / 207卷 / 01期

关键词：

dinuclear Cu(II) complex; catalyst; oxidative coupling reaction; polymerization; PPE;

D O I：

10.1016/S1381-1169(03)00463-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An oxidative coupling reaction intermediate, a mu-OCH3-bridged dinuclear(II) complex [CU2(mu-OCH3)(mu-OAC)(mu-CH3OH)(ClO4)Bipy(2)]-(ClO4) has been synthesized and characterized crystallographically and spectroscopically. This complex crystallizes in the monoclinic space group P2/n, with cell constants a = 7.914(2) Angstrom, b = 11.434(3) Angstrom, c = 34.336(10) Angstrom, alpha = 90, beta = 92.035(5), gamma = 90, V = 3105.3(14) Angstrom(3) and Z = 4. The dicopper(II) complex was investigated in the oxidative coupling reaction of 2,6-dimethylphenol (DMP) to polyphenylene ether (PPE) and shown to function as an effective catalyst. The product yield of 70% and PPE selectivity near 99% were achieved. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：15 / 20

页数：6

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