A spectacular increase in the polymerisation rate of 2,6-dimethylphenol induced by acetonitrile

被引：39

作者：

Gamez, P ^{[1
]}

Simons, C ^{[1
]}

Steensma, R ^{[1
]}

Driessen, WL ^{[1
]}

Challa, G ^{[1
]}

Reedijk, J ^{[1
]}

机构：

[1] Leiden Univ, Gorlaeus Labs, Leiden Inst Chem, NL-2300 RA Leiden, Netherlands

来源：

EUROPEAN POLYMER JOURNAL | 2001年 / 37卷 / 07期

关键词：

poly(2,6-dimethyl-1,4-phenylene ether); poly(1,4-phenylene ether); phenol oxidative coupling; acetonitrile; copper catalysis; 1-methylimidazole (meim);

D O I：

10.1016/S0014-3057(00)00259-7

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The oxidative polymerisations of 2,6-dimethylphenol with copper-(1-methylimidazole) complexes as the catalyst precursor compounds in different solvents showed the catalysts to be extremely active when using acetonitrile. Acetonitrile can act as a labile ligand for copper and also prevent the catalyst to become poisoned due to hydrolysis. Addition of increasing amounts of water leads to a progressive deactivation of the catalyst. (C) 2001 Published by Elsevier Science Ltd.

引用

页码：1293 / 1296

页数：4

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