Thermal analysis and spectroscopic characteristics of tetrabutylammonium tetrachloroferrate(III)

被引：29

作者：

Wyrzykowski, D

Maniecki, T

Pattek-Janczyk, A

Stanek, J

Warnke, Z

机构：

[1] Univ Gdansk, Fac Chem, PL-80952 Gdansk, Poland

[2] Tech Univ Lodz, Inst Gen & Ecol Chem, PL-90924 Lodz, Poland

[3] Jagiellonian Univ, Fac Chem, PL-30060 Krakow, Poland

[4] Jagiellonian Univ, M Smoluchowski Inst Phys, PL-30059 Krakow, Poland

来源：

THERMOCHIMICA ACTA | 2005年 / 435卷 / 01期

关键词：

tetrachloroferrate(III); thermal decomposition; IR; Raman; Mossbauer spectroscopy;

D O I：

10.1016/j.tca.2005.05.007

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The IR, far-IR, Raman and Mossbauer spectra have been utilized to identify a new compound consisting of a tetrachloroferrate(III) anion and a tetrabutylammonium cation [(C4H9)(4)N][FeCl4]. Its degradation has been studied by thermal analysis using TG, TG-MS, DTG and DTA, as well as DSC techniques. The measurements were run in static air and in argon atmosphere. Solid residues were identified by elemental analysis, far-IR and Mossbauer spectroscopy. The discussion was focused on processes proceeding during the first step of the thermal decomposition. (C) 2005 Elsevier B.V. All rights reserved.

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页码：92 / 98

页数：7

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