Conversion of Hemicellulose to Furfural and Levulinic Acid using Biphasic Reactors with Alkylphenol Solvents

被引:283
作者
Guerbuez, Elif I. [1 ]
Wettstein, Stephanie G. [1 ]
Dumesic, James A. [1 ]
机构
[1] Univ Wisconsin, Chem & Biol Engn Dept, Madison, WI 53706 USA
关键词
furfural; hemicelluloses; heterogeneous catalysis; levulinic acid; sustainable chemistry; GAMMA-VALEROLACTONE; TRANSPORTATION FUELS; LIQUID ALKANES; BIOMASS; HYDROGENATION; INTEGRATION; CATALYSTS; CELLULOSE; PLATFORM; BIOFUELS;
D O I
10.1002/cssc.201100608
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
Plans with plants: The hemicellulose fraction of lignocellulosic biomass is converted to furfural and levulinic acid using biphasic reactors with alkylphenol solvents that selectively partition furanic compounds from acidic aqueous solutions. The furfural and levulinic acid products are valuable compounds for a variety of chemical applications, and they serve as precursors for the synthesis of liquid transportation fuels. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:383 / 387
页数:5
相关论文
共 22 条
[1]
Production of Biofuels from Cellulose and Corn Stover Using Alkylphenol Solvents [J].
Alonso, David Martin ;
Wettstein, Stephanie G. ;
Bond, Jesse Q. ;
Root, Thatcher W. ;
Dumesic, James A. .
CHEMSUSCHEM, 2011, 4 (08) :1078-1081
[2]
Integrated Catalytic Conversion of γ-Valerolactone to Liquid Alkenes for Transportation Fuels [J].
Bond, Jesse Q. ;
Alonso, David Martin ;
Wang, Dong ;
West, Ryan M. ;
Dumesic, James A. .
SCIENCE, 2010, 327 (5969) :1110-1114
[3]
Production of levulinic acid and use as a platform chemical for derived products [J].
Bozell, JJ ;
Moens, L ;
Elliott, DC ;
Wang, Y ;
Neuenscwander, GG ;
Fitzpatrick, SW ;
Bilski, RJ ;
Jarnefeld, JL .
RESOURCES CONSERVATION AND RECYCLING, 2000, 28 (3-4) :227-239
[4]
Production of 5-hydroxymethylfurfural and furfural by dehydration of biomass-derived mono- and poly-saccharides [J].
Chheda, Juben N. ;
Roman-Leshkov, Yuriy ;
Dumesic, James A. .
GREEN CHEMISTRY, 2007, 9 (04) :342-350
[5]
Reactive Extraction of Levulinate Esters and Conversion to γ-Valerolactone for Production of Liquid Fuels [J].
Guerbuez, Elif I. ;
Alonso, David Martin ;
Bond, Jesse Q. ;
Dumesic, James A. .
CHEMSUSCHEM, 2011, 4 (03) :357-361
[6]
Production of liquid alkanes by aqueous-phase processing of biomass-derived carbohydrates [J].
Huber, GW ;
Chheda, JN ;
Barrett, CJ ;
Dumesic, JA .
SCIENCE, 2005, 308 (5727) :1446-1450
[7]
Lange J-P, 2010, ANGEW CHEM, V122, P4581, DOI DOI 10.1002/ANGE.201000655
[8]
Valeric Biofuels: A Platform of Cellulosic Transportation Fuels [J].
Lange, Jean-Paul ;
Price, Richard ;
Ayoub, Paul M. ;
Louis, Jurgen ;
Petrus, Leo ;
Clarke, Lionel ;
Gosselink, Hans .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (26) :4479-4483
[9]
Conversion of Furfuryl Alcohol into Ethyl Levulinate using Solid Acid Catalysts [J].
Lange, Jean-Paul ;
van de Graaf, Wouter D. ;
Haan, Rene J. .
CHEMSUSCHEM, 2009, 2 (05) :437-441
[10]
Furfural: Hemicellulose/xylosederived biochemical [J].
Mamman, Ajit Singh ;
Lee, Jong-Min ;
Kim, Yeong-Cheol ;
Hwang, In Taek ;
Park, No-Joong ;
Hwang, Young Kyu ;
Chang, Jong-San ;
Hwang, Jin-Soo .
BIOFUELS BIOPRODUCTS & BIOREFINING-BIOFPR, 2008, 2 (05) :438-454