Valeric Biofuels: A Platform of Cellulosic Transportation Fuels

被引：644

作者：

Lange, Jean-Paul ^{[1
]}

Price, Richard ^{[2
]}

Ayoub, Paul M. ^{[1
]}

Louis, Jurgen ^{[3
]}

Petrus, Leo ^{[1
]}

Clarke, Lionel ^{[2
]}

Gosselink, Hans ^{[1
]}

机构：

[1] Shell Global Solut Int BV, Shell Technol Ctr Amsterdam, NL-1031 HW Amsterdam, Netherlands

[2] Shell Global Solut UK, Shell Technol Ctr Thornton, Ince CH2 4NU, Cheshire, England

[3] Shell Global Solut Germany, Prod Anwendung & Entwicklung, D-21107 Hamburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 26期

关键词：

biofuels; biomass; heterogeneous catalysis; lignocellulose; sustainable chemistry; ACID-CATALYZED HYDROLYSIS; LEVULINIC ACID; GAMMA-VALEROLACTONE; CONVERSION; BIOMASS; CHEMISTRY; LIQUID; HYDROGENATION;

D O I：

10.1002/anie.201000655

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical equation presented) Fueling the future: Valeric esters can be produced by acid hydrolysis of lignocellulose to levulinic acid, followed by hydrogenation to valeric acid and its subsequent esterification (see scheme). Valeric biofuels are fully compatible for blending with gasoline or diesel, and have passed a road trial of 250 000 km. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4479 / 4483

页数：5

共 33 条

[1]

[Anonymous], 2007, CATAL RENEW, DOI DOI 10.1002/9783527621118.CH2

[2] Bioenergy expansion in the EU: Cost-effective climate change mitigation, employment creation and reduced dependency on imported fuels [J].

Berndes, Goran ;

Hansson, Julia .

ENERGY POLICY, 2007, 35 (12) :5965-5979

[3] Integrated Catalytic Conversion of γ-Valerolactone to Liquid Alkenes for Transportation Fuels [J].

Bond, Jesse Q. ;

Alonso, David Martin ;

Wang, Dong ;

West, Ryan M. ;

Dumesic, James A. .

SCIENCE, 2010, 327 (5969) :1110-1114

[4] Maximising opportunities in supercritical chemistry:: the continuous conversion of levulinic acid to γ-valerolactone in CO2 [J].

Bourne, Richard A. ;

Stevens, James G. ;

Ke, Jie ;

Poliakoff, Martyn .

CHEMICAL COMMUNICATIONS, 2007, (44) :4632-4634

[5] Levulinic acid production from wheat straw [J].

Chang, Chun ;

Cen, Peilin ;

Ma, Xiaojian .

BIORESOURCE TECHNOLOGY, 2007, 98 (07) :1448-1453

[6]

Dale BE, 2006, BIOREFINERIES - INDUSTRIAL PROCESSES AND PRODUCTS: STATUS QUO AND FUTURE DIRECTIONS, VOL 1, P41

[7]

GALGHATGI GT, 2005010239 SOC AUT E

[8] Experimental and kinetic modelling studies on the acid-catalysed hydrolysis of the water hyacinth plant to levulinic acid [J].

Girisuta, B. ;

Danon, B. ;

Manurung, R. ;

Janssen, L. P. B. M. ;

Heeres, H. J. .

BIORESOURCE TECHNOLOGY, 2008, 99 (17) :8367-8375

[9] Kinetic study on the acid-catalyzed hydrolysis of cellulose to levulinic acid [J].

Girisuta, B. ;

Janssen, L. P. B. M. ;

Heeres, H. J. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2007, 46 (06) :1696-1708

[10]

Hayes DJ, 2006, BIOREFINERIES - INDUSTRIAL PROCESSES AND PRODUCTS: STATUS QUO AND FUTURE DIRECTIONS, VOL 1, P139

← 1 2 3 4 →