Applied crystallography solutions to problems in industrial solid-state chemistry - Case examples with ceramics, cements and zeolites

被引:28
作者
Barnes, P
Turrillas, X
Jupe, AC
Colston, SL
OConnor, D
Cernik, RJ
Livesey, P
Hall, C
Bates, D
Dennis, R
机构
[1] CCLRC, DARESBURY LAB, WARRINGTON WA4 4AD, CHESHIRE, ENGLAND
[2] CASTLE CEMENT RIBBLESDALE LTD, CLITHEROE BB7 4QF, LANCS, ENGLAND
[3] SCHLUMBERGER CAMBRIDGE RES LTD, CAMBRIDGE CB3 0EL, ENGLAND
[4] BRITISH GAS PLC, GAS RES CTR, LOUGHBOROUGH LE11 3QU, LEICS, ENGLAND
[5] SYNTHOMER LTD, HARLOW CM20 2BH, ESSEX, ENGLAND
来源
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1996年 / 92卷 / 12期
关键词
D O I
10.1039/ft9969202187
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We show that a number of processes involved in the field of industrial solid-state chemistry can be successfully studied in situ using a range of crystallographic and related techniques. The adaptation of relevant equipment to reproduce the process environment at the sample is a crucial part of the approach. Examples are given, involving the synthesis of zirconia-based ceramics, hydration of cements, and dehydration of zeolites, where successful applications of this approach have uncovered new structural/kinetic aspects concerning seemingly well established industrial processes.
引用
收藏
页码:2187 / 2196
页数:10
相关论文
共 44 条
  • [31] CONVERSION OF CALCIUM ALUMINATE CEMENT HYDRATES REEXAMINED WITH SYNCHROTRON ENERGY-DISPERSIVE DIFFRACTION
    RASHID, S
    BARNES, P
    BENSTED, J
    TURRILLAS, X
    [J]. JOURNAL OF MATERIALS SCIENCE LETTERS, 1994, 13 (17) : 1232 - 1234
  • [32] Rashid S., 1992, ADV CEM RES, DOI [10.1680/adcr.1992.4.14.61, DOI 10.1680/ADCR.1992.4.14.61]
  • [33] LINE PROFILES OF NEUTRON POWDER-DIFFRACTION PEAKS FOR STRUCTURE REFINEMENT
    RIETVELD, HM
    [J]. ACTA CRYSTALLOGRAPHICA, 1967, 22 : 151 - &
  • [34] COMPOSITE MECHANISM OF POLYMER-MODIFIED CEMENT
    SAKAI, E
    SUGITA, J
    [J]. CEMENT AND CONCRETE RESEARCH, 1995, 25 (01) : 127 - 135
  • [35] Scherrer P., 1918, WEIDMANNSCHE BUCHHAN, V26, P98
  • [36] SMYTH JR, 1990, AM MINERAL, V75, P522
  • [37] Taylor H.F.W., 1964, The chemistry of cements
  • [38] Taylor H.F. W., 1990, CEMENT CHEM
  • [39] TAYLOR HFW, 1994, ENG F M NEW HAMPSH
  • [40] NEUTRON THERMODIFFRACTOMETRY AND SYNCHROTRON ENERGY-DISPERSIVE DIFFRACTION STUDIES OF ZIRCONIUM HYDROXIDE CALCINATION
    TURRILLAS, X
    BARNES, P
    TARLING, SE
    JONES, SL
    NORMAN, CJ
    RITTER, C
    [J]. JOURNAL OF MATERIALS SCIENCE LETTERS, 1993, 12 (04) : 223 - 226