Preparation of graphene-polyaniline composites by simple chemical procedure and its improved field emission properties

被引：119

作者：

Goswami, S. ^{[1
]}

Maiti, U. N. ^{[1
]}

Maiti, S. ^{[1
]}

Nandy, S. ^{[1
]}

Mitra, M. K. ^{[2
]}

Chattopadhyay, K. K. ^{[1
,2
]}

机构：

[1] Jadavpur Univ, Dept Phys, Thin Film & Nanosci Lab, Kolkata 700032, India

[2] Jadavpur Univ, Sch Mat Sci & Nanotechnol, Kolkata 700032, India

来源：

CARBON | 2011年 / 49卷 / 07期

关键词：

ELECTROCHEMICAL PROPERTIES; FACILE SYNTHESIS; FILMS; OXIDE; TRANSPARENT; NANOFIBERS;

D O I：

10.1016/j.carbon.2011.01.055

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Graphene-polyaniline composites have been synthesized using simple chemical procedure in two different ways (i) by mixing of the pre-synthesized graphene and polyaniline nanofibers and (ii) by in situ polymerization in presence of graphite oxide followed by further reduction. Detailed optical spectroscopic studies of the synthesized composites along with the pristine polyaniline nanofibers were performed by Fourier transformed infrared spectroscopy and UV-vis spectroscopy. The structural and morphological characterizations were performed by X-ray diffraction, transmission electron microscope measurements and field emission scanning electron microscope measurements, respectively while the chemical characters were studied by X-ray photoelectron spectroscopic measurement. The graphene-polyaniline composite retained the photoluminescence property of the as synthesized polyaniline nanofibers. The electron field emission property of the composite showed marked improvement compared to pristine polyaniline fibers with a turn-on field as low as 3.91 V/mu m at a current density of 1 mu A/cm(2). The field enhancement factor was found to be 7012 which is much higher for the case of a polymer based composite. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：2245 / 2252

页数：8

共 41 条

[21] Novel low temperature synthesis of ZnO nanostructures and its efficient field emission property [J].

Maiti, U. N. ;

Ahmed, Sk. F. ;

Mitra, M. K. ;

Chattopadhyay, K. K. .

MATERIALS RESEARCH BULLETIN, 2009, 44 (01) :134-139

[22] Reduced graphene oxide by chemical graphitization [J].

Moon, In Kyu ;

Lee, Junghyun ;

Ruoff, Rodney S. ;

Lee, Hyoyoung .

NATURE COMMUNICATIONS, 2010, 1

[23]

PEDRO GR, 2001, ADV MATER, V13, P163

[24] POLYMER LIGHT-EMITTING ELECTROCHEMICAL-CELLS [J].

PEI, QB ;

YU, G ;

ZHANG, C ;

YANG, Y ;

HEEGER, AJ .

SCIENCE, 1995, 269 (5227) :1086-1088

[25] Some aspects of preparation methods and properties of polyaniline blends and composites with organic polymers [J].

Pud, A ;

Ogurtsov, N ;

Korzhenko, A ;

Shapoval, G .

PROGRESS IN POLYMER SCIENCE, 2003, 28 (12) :1701-1753

[26] Correlation between Resistance and Field Emission Performance of Individual ZnO One-Dimensional Nanostructures [J].

She, Juncong ;

Xiao, Zhiming ;

Yang, Yuhua ;

Deng, Shaozhi ;

Chen, Jun ;

Yang, Guowei ;

Xu, Ningsheng .

ACS NANO, 2008, 2 (10) :2015-2022

[27] Polyaniline, a dynamic block copolymer: key to attaining its intrinsic conductivity? [J].

Shimano, JY ;

MacDiarmid, AG .

SYNTHETIC METALS, 2001, 123 (02) :251-262

[28] Synthesis of water soluble graphene [J].

Si, Yongchao ;

Samulski, Edward T. .

NANO LETTERS, 2008, 8 (06) :1679-1682

[29] Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide [J].

Stankovich, Sasha ;

Dikin, Dmitriy A. ;

Piner, Richard D. ;

Kohlhaas, Kevin A. ;

Kleinhammes, Alfred ;

Jia, Yuanyuan ;

Wu, Yue ;

Nguyen, SonBinh T. ;

Ruoff, Rodney S. .

CARBON, 2007, 45 (07) :1558-1565

[30] Graphene-based composite materials [J].

Stankovich, Sasha ;

Dikin, Dmitriy A. ;

Dommett, Geoffrey H. B. ;

Kohlhaas, Kevin M. ;

Zimney, Eric J. ;

Stach, Eric A. ;

Piner, Richard D. ;

Nguyen, SonBinh T. ;

Ruoff, Rodney S. .

NATURE, 2006, 442 (7100) :282-286

← 1 2 3 4 5 →