Copper(0)-Mediated Living Radical Polymerization of Methyl Methacrylate in a Non-polar Solvent

被引：59

作者：

Hornby, Ben D. ^{[1
]}

West, Andrew G. ^{[1
]}

Tom, Jessica C. ^{[1
]}

Waterson, Carl ^{[2
]}

Harrisson, Simon ^{[3
]}

Perrier, Sebastien ^{[1
]}

机构：

[1] Univ Sydney, Sch Chem, Key Ctr Polymers & Colloids, Sydney, NSW 2006, Australia

[2] Infineum Int Ltd, Milton Hill Business & Technol Ctr, Abingdon OX13 6BB, Oxon, England

[3] CSIRO Mol & Hlth Technol, Clayton, Vic 3168, Australia

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2010年 / 31卷 / 14期

关键词：

copper(0); living radical polymerization; methyl methacrylate; non-polar solvent; room temperature; NITROXIDE-MEDIATED POLYMERIZATION; ELECTRON-TRANSFER; SULFONYL CHLORIDES; SET-LRP; ACRYLATE; 25-DEGREES-C; COPOLYMER; ACID; ATRP;

D O I：

10.1002/marc.201000031

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The metal catalyzed polymerization of methyl methacrylate using Cu(0) as the catalyst source has been investigated in toluene. This work looks at polymerizations in a non-polar medium allowing control over the molecular weight and polydispersity with a 4-fold reduction in catalyst concentration versus conventional ATRP, while the use of an active ligand allows the reaction to proceed at room temperature. The use of an excess of PMDETA ligand allows for high conversions, and the addition of a small amount of CuBr2 enhances living characteristics, enabling efficient chain extension.

引用

页码：1276 / 1280

页数：5

共 33 条

[1] Evidence for the low thermal stability of poly(methyl methacrylate) polymer produced by atom transfer radical polymerisation [J].

Borman, CD ;

Jackson, AT ;

Bunn, A ;

Cutter, AL ;

Irvine, DJ .

POLYMER, 2000, 41 (15) :6015-6020

[2] First nitroxide-mediated controlled free-radical polymerization of acrylic acid [J].

Couvreur, L ;

Lefay, C ;

Belleney, J ;

Charleux, B ;

Guerret, O ;

Magnet, S .

MACROMOLECULES, 2003, 36 (22) :8260-8267

[3] The persistent radical effect in ''living'' radical polymerization [J].

Fischer, H .

MACROMOLECULES, 1997, 30 (19) :5666-5672

[4] Controlled/''living'' radical polymerization of methyl methacrylate by atom transfer radical polymerization [J].

Grimaud, T ;

Matyjaszewski, K .

MACROMOLECULES, 1997, 30 (07) :2216-2218

[5] First effective nitroxide-mediated polymerization of methyl methacrylate [J].

Guillaneuf, Yohann ;

Gigmes, Didier ;

Marque, Sylvain R. A. ;

Astolfi, Paola ;

Greci, Lucedio ;

Tordo, Paul ;

Bertin, Denis .

MACROMOLECULES, 2007, 40 (09) :3108-3114

[6] Nitroxide-mediated polymerization of methyl methacrylate using an SG1-based alkoxyamine: How the penultimate effect could lead to uncontrolled and unliving polymerization [J].

Guillaneuf, Yohann ;

Gigmes, Didier ;

Marque, Sylvain R. A. ;

Tordo, Paul ;

Bertin, Denis .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 2006, 207 (14) :1278-1288

[7] Low-temperature living "radical" polymerization (atom transfer polymerization) of methyl methacrylate mediated by copper(I) N-alkyl-2-pyridylmethanimine complexes [J].

Haddleton, DM ;

Kukulj, D ;

Duncalf, DJ ;

Heming, AM ;

Shooter, AJ .

MACROMOLECULES, 1998, 31 (16) :5201-5205

[8] New polymer synthesis by nitroxide mediated living radical polymerizations [J].

Hawker, CJ ;

Bosman, AW ;

Harth, E .

CHEMICAL REVIEWS, 2001, 101 (12) :3661-3688

[9] Molecular spectroscopic characterisation of poly(methyl methacrylate) generated by means of atom transfer radical polymerisation (ATRP) [J].

Jackson, AT ;

Bunn, A ;

Priestnall, IM ;

Borman, CD ;

Irvine, DJ .

POLYMER, 2006, 47 (04) :1044-1054

[10] Activators regenerated by electron transfer for atom transfer radical polymerization of styrene [J].

Jakubowski, W ;

Min, K ;

Matyjaszewski, K .

MACROMOLECULES, 2006, 39 (01) :39-45

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