Highly active, stable, catalysts for the Heck reaction; further suggestions on the mechanism

被引：194

作者：

Shaw, BL ^{[1
]}

Perera, SD ^{[1
]}

Staley, EA ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 13期

关键词：

D O I：

10.1039/a802642d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tri(1-naphthyl)phosphine gives palladacycles which are very active catalysts for Heck reactions; mechanisms based on a Pd(II)-Pd(IV) cycle are proposed and a new, very efficient method of separating the product from the catalyst has been devised, which involves treatment with cyanide ion.

引用

页码：1361 / 1362

页数：2

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