Heteropolycompound-based catalysts: A blend of acid and oxidizing properties

被引：152

作者：

Cavani, F ^{[1
]}

机构：

[1] Univ Bologna, Dipartimento Chim Ind & Mat, I-40136 Bologna, Italy

来源：

CATALYSIS TODAY | 1998年 / 41卷 / 1-3期

关键词：

heteropolycompound; heteropolyoxometalate; heterogeneous catalysis; homogeneous catalysis; acid catalysis; oxidation catalysis;

D O I：

10.1016/S0920-5861(98)00039-X

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This review reports some aspects of the synthesis, chemical-physical properties and reactivity of heteropolyoxometalates. Particular attention is given to most recent developments in the use of heteropolycompounds as heterogeneous and homogeneous catalysts for the selective oxidation of hydrocarbons. (C) 1998 Elsevier Science B.V. All rights reserved.

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页码：73 / 86

页数：14

相关论文

共 44 条

[21] HOMOGENEOUS CATALYSTS BASED ON HETEROPOLY ACIDS (REVIEW) [J].

KOZHEVNIKOV, IV ;

MATVEEV, KI .

APPLIED CATALYSIS, 1983, 5 (02) :135-150

[22] HETEROPOLY ACIDS AND RELATED-COMPOUNDS AS CATALYSTS FOR FINE CHEMICAL SYNTHESIS [J].

KOZHEVNIKOV, IV .

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1995, 37 (02) :311-352

[23] HIGHLY OXIDATION RESISTANT INORGANIC-PORPHYRIN ANALOG POLYOXOMETALATE OXIDATION CATALYSTS .1. THE SYNTHESIS AND CHARACTERIZATION OF AQUEOUS-SOLUBLE POTASSIUM-SALTS OF ALPHA-2-P2W17O61(MN+.OH2)(N-10) AND ORGANIC-SOLVENT SOLUBLE TETRA-NORMAL-BUTYLAMMONIUM SALTS OF ALPHA-2-P2W17O61(MN+.BR)(N-11) (M = MN3+, FE3+, CO2+, NI2+, CU2+) [J].

LYON, DK ;

MILLER, WK ;

NOVET, T ;

DOMAILLE, PJ ;

EVITT, E ;

JOHNSON, DC ;

FINKE, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (19) :7209-7221

[24]

Lyons J. E., 1989, U. S. Patent, Patent No. 4803187

[25]

MISONO M, 1993, CHEMTECH, V23, P23

[26] HETEROGENEOUS CATALYSIS BY HETEROPOLY COMPOUNDS OF MOLYBDENUM AND TUNGSTEN [J].

MISONO, M .

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1987, 29 (2-3) :269-321

[27]

Misono M, 1997, STUD SURF SCI CATAL, V110, P35

[28]

Misono M., 1993, STUD SURF SCI CATAL, V75, P69

[29] Oxidation of isobutane catalyzed by CsxH3-xPMo12O40-based heteropoly compounds [J].

Mizuno, N ;

Tateishi, M ;

Iwamoto, M .

JOURNAL OF CATALYSIS, 1996, 163 (01) :87-94

[30] HETEROPOLYANIONS IN CATALYSIS [J].

MIZUNO, N ;

MISONO, M .

JOURNAL OF MOLECULAR CATALYSIS, 1994, 86 (1-3) :319-342

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