A trifunctional mesoporous silica-based, highly active catalyst for one-pot, three-step cascade reactions

被引：54

作者：

Biradar, Ankush V. ^{[1
]}

Patil, Vijayshinha S. ^{[1
]}

Chandra, Prakash ^{[1
]}

Doke, Dhananjay S. ^{[1
]}

Asefa, Tewodros ^{[2
,3
,4
]}

机构：

[1] CSIR, Natl Chem Lab, Catalysis Div, Pune 411008, Maharashtra, India

[2] Rutgers State Univ, Dept Chem & Chem Biol, Piscataway, NJ 08854 USA

[3] Rutgers State Univ, Dept Chem & Biochem Engn, Piscataway, NJ 08854 USA

[4] Rutgers State Univ, Inst Adv Mat Devices & Nanotechnol, Piscataway, NJ 08854 USA

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 40期

基金：

美国国家科学基金会;

关键词：

BASIC SITES; ACID; NANOCOMPOSITE; OXIDATION;

D O I：

10.1039/c5cc01694k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the synthesis of a trifunctional catalyst containing amine, sulphonic acid and Pd nanoparticle catalytic groups anchored on the pore walls of SBA-15. The catalyst efficiently catalyzes one-pot three-step cascade reactions comprising deacetylation, Henry reaction and hydrogenation, giving up to similar to 100% conversion and 92% selectivity to the final product.

引用

页码：8496 / 8499

页数：4

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