Epoxidation of α,β-unsaturated ketones in water.: An environmentally benign protocol

被引：68

作者：

Fioroni, G ^{[1
]}

Fringuelli, F ^{[1
]}

Pizzo, F ^{[1
]}

Vaccaro, L ^{[1
]}

机构：

[1] Univ Perugia, Dept Chem, I-06100 Perugia, Italy

来源：

GREEN CHEMISTRY | 2003年 / 5卷 / 04期

关键词：

D O I：

10.1039/b303883a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An easy, cheap procedure is proposed for the epoxidation of alpha,beta-unsaturated ketones in water as the sole reaction medium and using bases such as NaOH and CTAOH as promoting agents and hydrogen peroxide as oxidant. By using solely water, the reaction medium can be recycled which is important for reducing wastes. An example of an alpha-functionalization of alpha,beta-unsaturated ketones by a one-pot procedure in water is reported.

引用

页码：425 / 428

页数：4

共 66 条

[61] EPOXIDATION AND CLEAVAGE OF ALPHA,BETA-UNSATURATED KETONES WITH ALKALINE HYDROGEN PEROXIDE [J].