Formation of two (6,3) networks showing structural diversity, Borromean topology and conformational chirality in the same crystal

被引：83

作者：

Zhang, Xue-Li

Guo, Cui-Ping

Yang, Qing-Yuan

Wang, Wei

Liu, Wei-Sheng

Kang, Bei-Sheng

Su, Cheng-Yong ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, State Key Lab Optoelect Mat & Technol, MOE Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Peoples R China

[2] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 41期

关键词：

D O I：

10.1039/b709118d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of two tripodal ligands, 2,4,6-tris(4-((2-methyl-benzimidazol-1-yl) methyl) phenyl)- 1,3,5-triazine (L-1) and 1,3,5-tris( 4(( 2-methyl- benzimidazol-1-yl) methyl) phenyl) benzene ( L 2), with AgSbF6 led to formation of two types ( 6,3) networks in one single crystal, of which one is three-fold Borromean topologically entangled while the other is independent, showing the same chirality and sandwiched Borromean stacking.

引用

页码：4242 / 4244

页数：3

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