Three-dimensional architectures of intertwined planar coordination polymers: the first case of interpenetration involving two different bidimensional polymeric motifs

被引:87
作者
Carlucci, L
Ciani, G
Proserpio, DM
机构
[1] Dipartimento Chim Strutturale & Stereochim Inorga, I-20133 Milan, Italy
[2] Ctr CNR, I-20133 Milan, Italy
关键词
D O I
10.1039/a807924b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The novel bidimensional coordination polymers [Zn(azpy)(2)(H2O)(2)]SiF6. H2O and [Ni(azpy)(2)(NO3)(2)](2)[Ni-2(azpy)(3)(NO3)(4)]. 4CH(2)Cl(2), assembled with trans-4,4'-azobis(pyridine) (azpy), show inclined interpenetration of their layers, i.e. (4,4) planes in the former species, and (4,4) and (6,3) planes, in the second one, which represents the first example of intertwining of different two-dimensional coordination motifs.
引用
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页码:1319 / 1321
页数:3
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