Reduction of sulfoxides with boranes catalyzed by MoO2Cl2

被引：92

作者：

Fernandes, Ana C. ^{[1
]}

Romao, Carlos C. ^{[1
]}

机构：

[1] Univ Nova Lisboa, Inst Tecnol Quim & Biol, EAN, P-2781901 Oeiras, Portugal

来源：

TETRAHEDRON LETTERS | 2007年 / 48卷 / 52期

关键词：

reduction; sulfoxides; dioxomolybdenum dichloride; boranes; B-H activation;

D O I：

10.1016/j.tetlet.2007.10.106

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first example of an organic reduction with boranes catalyzed by a high valent oxo-complex is reported. The systems catecholborane/MoO2Cl2(H2O)(2) and BH3 center dot THF/MoO2Cl2 (5 mol %) proved to be very efficient for the reduction of sulfoxides to the corresponding sulfides in excellent yields. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：9176 / 9179

页数：4

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