Fast lithium ion conduction in garnet-type Li7La3Zr2O12

被引：2630

作者：

Murugan, Ramaswamy

Thangadurai, Venkataraman

Weppner, Werner

机构：

[1] Univ Kiel, Fac Engn, Chair Sensors & Solid State Ion, D-24143 Kiel, Germany

[2] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 41期

关键词：

electrochemistry; garnet; ionic conduction; lithium batteries; solid electrolytes;

D O I：

10.1002/anie.200701144

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Low activation energy and fast lithium ion conduction have been observed for the new compound Li7La3Zr 2O12. Relative to previously reported lithium garnets, the solid electrolyte shows a larger cubic lattice constant, higher lithium ion concentration, lower degree of chemical interaction between the Li+ ions and the other lattice constituents, and higher densification. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7778 / 7781

页数：4