Phosphonium tosylates as solvents for the Diels-Alder reaction

被引：87

作者：

Ludley, P ^{[1
]}

Karodia, N ^{[1
]}

机构：

[1] Univ Bradford, Dept Chem & Forens Sci, Bradford BD7 1DP, W Yorkshire, England

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 10期

关键词：

Diels-Alder reactions; ionic liquids; phosphonium salts; regioselectivity;

D O I：

10.1016/S0040-4039(01)00064-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Phosphonium tosylates have been investigated as solvents for the Diels-Alder reactions of isoprene with methyl acrylate, but-3-en-2-one and acrylonitrile. The reactions with oxygen-containing dienophiles showed high regioselectivity. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：2011 / 2014

页数：4

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