Transition-Metal-Catalyzed Carboxylation of C-H Bonds

被引：172

作者：

Ackermann, Lutz ^{[1
]}

机构：

[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 17期

关键词：

C-H activation; carbon dioxide; copper; homogeneous catalysis; gold; CARBENE COPPER(I) COMPLEXES; CARBON-DIOXIDE; ORGANOZINC REAGENTS; ARENES; CO2; HETEROCYCLES;

D O I：

10.1002/anie.201007883

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

CO2 in a fix: Gold and copper complexes of N-heterocyclic carbenes recently enabled efficient direct carboxylation of (hetero)arenes having moderately acidic C-H bonds under remarkably mild reaction conditions (IPr=1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene). © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3842 / 3844

页数：3

共 31 条

[1]

Ackermann L., 2009, ANGEW CHEM, V121, P9976, DOI DOI 10.1002/ANGE.200902996

[2] Metal-catalyzed direct alkylations of (hetero)arenes via C-H bond cleavages with unactivated alkyl halides [J].

Ackermann, Lutz .

CHEMICAL COMMUNICATIONS, 2010, 46 (27) :4866-4877

[3] Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by C-H Bond Cleavage [J].

Ackermann, Lutz ;

Vicente, Ruben ;

Kapdi, Anant R. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (52) :9792-9826

[4]

[Anonymous], 2010, ANGEW CHEM-GER EDIT

[5]

[Anonymous], 2010, ANGEW CHEM

[6]

[Anonymous], 2010, ANGEW CHEM

[7] CO2 as Raw Material [J].

Bazzanella, Alexis ;

Kramer, Dennis ;

Peters, Martina .

NACHRICHTEN AUS DER CHEMIE, 2010, 58 (12) :1226-1230

[8] Carboxylation of N-H/C-H Bonds Using N-Heterocyclic Carbene Copper(I) Complexes [J].

Boogaerts, Ine I. F. ;

Fortman, George C. ;

Furst, Marc R. L. ;

Cazin, Catherine S. J. ;

Nolan, Steven P. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (46) :8674-8677

[9] Carboxylation of C-H Bonds Using N-Heterocyclic Carbene Gold(I) Complexes [J].

Boogaerts, Ine I. F. ;

Nolan, Steven P. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (26) :8858-+

[10]

Correa A., 2009, ANGEW CHEM, V121, P6317

← 1 2 3 4 →