Tuneable mechanical properties in low molecular weight gels

被引：85

作者：

Chen, Lin ^{[1
]}

Raeburn, Jaclyn ^{[1
]}

Sutton, Sam ^{[1
]}

Spiller, David G. ^{[2
]}

Williams, James ^{[1
]}

Sharp, James S. ^{[3
]}

Griffiths, Peter C. ^{[4
]}

Heenan, Richard K. ^{[5
]}

King, Stephen M. ^{[5
]}

Paul, Alison ^{[4
]}

Furzeland, Steve ^{[6
]}

Atkins, Derek ^{[6
]}

Adams, Dave J. ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

[2] Univ Liverpool, Sch Biol Sci, Ctr Cell Imaging, Liverpool L69 7ZB, Merseyside, England

[3] Univ Nottingham, Nanotechnol & NanoSci Ctr, Sch Phys & Astron & Nottingham, Nottingham NG7 2RD, England

[4] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales

[5] Sci & Technol Facil Council, Rutherford Appleton Lab, Didcot OX11 0QX, Oxon, England

[6] Unilever R&D, Sharnbrook MK44 1LQ, Beds, England

来源：

SOFT MATTER | 2011年 / 7卷 / 20期

基金：

英国工程与自然科学研究理事会;

关键词：

ANGLE NEUTRON-SCATTERING; DYNAMIC LIGHT-SCATTERING; ORGANOGELS; HYDROGELS; GELATION; DIPEPTIDE; ARCHITECTURE; NAPHTHALENE; NETWORKS; GELATORS;

D O I：

10.1039/c1sm05827d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

The mechanical properties of gels are critical to the final targeted applications. Depending on the application, different properties may be required. Here, we show that the mechanical strength and ability to recover of gels formed using a low molecular weight gelator can be controlled by two independent factors (i) the volume fraction of co-solvent (in this case DMSO) in the system and (ii) the temperature cycle used. These differences correlate with the large scale structure of the network that is formed from the self-assembled fibres. This opens up the potential to prepare gels with very different properties at the same final conditions, allowing the effect of microstructure to be probed.

引用

页码：9721 / 9727

页数：7

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