A highly flexible route to tricyclo[4.3.1.03,7]-, and tricyclo[4,3.0.04,10]decanes -: A short synthesis of pupukean-2-one

被引：12

作者：

Biju, PJ ^{[1
]}

Rao, GSRS ^{[1
]}

机构：

[1] Indian Inst Sci, Dept Organ Chem, Bangalore 560012, Karnataka, India

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 01期

关键词：

D O I：

10.1016/S0040-4039(98)80053-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient strategy for the construction of tricyclo[4.3.1.0(3,7)]-, and tricyclo[4.3.0.0(4,10)]decanes is described which involves a novel one-pot tandem acid-catalyzed rearrangement followed by an ene cyclization as key step and is exemplified by the total synthesis of pupukean-2-one 3. (C) 1998 Elsevier Science Ltd. All rights reserved.

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页码：181 / 184

页数：4

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