A new aluminum hydroxide octamer, [Al8(OH)14(H2O)18](SO4)5•16H2O

被引:73
作者
Casey, WH [1 ]
Olmstead, MM
Phillips, BL
Phillips, L
机构
[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
[2] Univ Calif Davis, Dept Geol, Davis, CA 95616 USA
[3] SUNY Stony Brook, Dept Geosci, Stony Brook, NY 11794 USA
关键词
D O I
10.1021/ic050426k
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new aluminum hydroxide cluster with eight Al(III) ions linked together by a series of hydroxyl bridges as a sulfate salt has been synthesized from aqueous solution and characterized by X-ray crystallography and (27)AI NMR spectroscopy.
引用
收藏
页码:4888 / 4890
页数:3
相关论文
共 29 条
[21]   Bonding and reactivity at oxide mineral surfaces from model aqueous complexes [J].
Phillips, BL ;
Casey, WH ;
Karlsson, M .
NATURE, 2000, 404 (6776) :379-382
[22]   Speciation and thermal transformation in alumina sols:: Structures of the polyhydroxyoxoaluminum cluster [Al30O8(OH)56(H2O)26]18+ and its δ-Keggin moiete [J].
Rowsell, J ;
Nazar, LF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (15) :3777-3778
[23]   Synthesis, structures and properties of hydrolytic Al(III) aggregates and Fe(III) analogues formed with iminodiacetate-based chelating ligands [J].
Schmitt, W ;
Jordan, PA ;
Henderson, RK ;
Moore, GR ;
Anson, CE ;
Powell, AK .
COORDINATION CHEMISTRY REVIEWS, 2002, 228 (02) :115-126
[24]  
Schmitt W, 2001, ANGEW CHEM INT EDIT, V40, P3578
[25]  
Seichter W, 1998, EUR J INORG CHEM, P795
[26]  
Sheldrick G., 2004, TWINABS
[27]  
Sheldrick G. M., 2005, CELLNOW
[28]  
SHELDRICK GM, 1997, SHELXS90 SHELXL97 U
[29]  
VONSCHONHERR S, 1983, ANORG ALLG CHEM, V503, P37