Polymer-supported nitroxyl radical catalyst for selective aerobic oxidation of primary alcohols to aldehydes

被引：80

作者：

Gilhespy, M ^{[1
]}

Lok, M ^{[1
]}

Baucherel, X ^{[1
]}

机构：

[1] Johnson Matthey Catalysts, Billingham TS23 1LB, Cleveland, England

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 08期

关键词：

D O I：

10.1039/b415902k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

PS-TEMPO, a polymer-supported 2,2,6,6-tetramethyl-piperidine-N-oxyl (TEMPO), was successfully applied as a recyclable, active and selective catalyst for the oxidation of primary aliphatic and benzylic alcohols to aldehydes by molecular oxygen in the presence of Co(NO3)(2) and Mn(NO3)(2) as co-catalysts.

引用

页码：1085 / 1086

页数：2

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