Electronic and geometric corrugation of periodically rippled, self-nanostructured graphene epitaxially grown on Ru(0001)

被引:125
作者
Borca, Bogdana [1 ]
Barja, Sara [1 ,2 ]
Garnica, Manuela [1 ,2 ]
Minniti, Marina [2 ]
Politano, Antonio [2 ]
Rodriguez-Garcia, Josefa M. [1 ]
Hinarejos, Juan Jose [1 ,3 ]
Farias, Daniel [1 ,3 ]
Vazquez de Parga, Amadeo L. [1 ,2 ,3 ]
Miranda, Rodolfo [1 ,2 ,3 ]
机构
[1] Univ Autonoma Madrid, Dept Fis Mat Condensada, E-28049 Madrid, Spain
[2] IMDEA Nanociencia, Madrid 28049, Spain
[3] Univ Autonoma Madrid, Inst Ciencia Mat Nicolas Cabrera, E-28049 Madrid, Spain
来源
NEW JOURNAL OF PHYSICS | 2010年 / 12卷
关键词
SCATTERING; HELIUM;
D O I
10.1088/1367-2630/12/9/093018
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Graphene epitaxially grown on Ru(0001) displays a remarkably ordered pattern of hills and valleys in scanning tunneling microscopy (STM) images. The extent to which the observed 'ripples' are structural or electronic in origin has been much disputed recently. A combination of ultrahigh-resolution STM images and helium atom diffraction data shows that (i) the graphene lattice is rotated with respect to the lattice of Ru and (ii) the structural corrugation as determined from He diffraction is substantially smaller (0.15 angstrom) than predicted (1.5 angstrom) or reported from x-ray diffraction or low-energy electron diffraction. The electronic corrugation, on the contrary, is strong enough to invert the contrast between hills and valleys above +2.6V as new, spatially localized electronic states enter the energy window of the STM. The large electronic corrugation results in a nanostructured periodic landscape of electron and hole pockets.
引用
收藏
页数:15
相关论文
共 37 条
[1]   HYBRIDIZATION INTERACTION BETWEEN HELIUM AND A METAL-SURFACE [J].
ANNETT, JF ;
HAYDOCK, R .
PHYSICAL REVIEW B, 1986, 34 (10) :6860-6868
[2]   STUDY OF GAS-GRAPHITE POTENTIAL BY MEANS OF HELIUM ATOM DIFFRACTION [J].
BOATO, G ;
CANTINI, P ;
TATAREK, R .
PHYSICAL REVIEW LETTERS, 1978, 40 (13) :887-889
[3]   Potential Energy Landscape for Hot Electrons in Periodically Nanostructured Graphene [J].
Borca, B. ;
Barja, S. ;
Garnica, M. ;
Sanchez-Portal, D. ;
Silkin, V. M. ;
Chulkov, E. V. ;
Hermanns, C. F. ;
Hinarejos, J. J. ;
Vazquez de Parga, A. L. ;
Arnau, A. ;
Echenique, P. M. ;
Miranda, R. .
PHYSICAL REVIEW LETTERS, 2010, 105 (03)
[4]   Periodically modulated geometric and electronic structure of graphene on Ru(0001) [J].
Borca, B. ;
Barja, S. ;
Garnica, M. ;
Hinarejos, J. J. ;
Vazquez de Parga, A. L. ;
Miranda, R. ;
Guinea, F. .
SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 2010, 25 (03)
[5]   Reactivity of periodically rippled graphene grown on Ru(0001) [J].
Borca, B. ;
Calleja, F. ;
Hinarejos, J. J. ;
de Parga, A. L. Vazquez ;
Miranda, R. .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2009, 21 (13)
[6]   Relationship between strain and the surface electronic structure of Cu(111) films on Ru(0001):: Theory and experiment -: art. no. 125412 [J].
Calleja, F ;
García-Suárez, VM ;
Hinarejos, JJ ;
Ferrer, J ;
de Parga, ALV ;
Miranda, R .
PHYSICAL REVIEW B, 2005, 71 (12)
[7]   Contrast reversal and shape changes of atomic adsorbates measured with scanning tunneling microscopy [J].
Calleja, F ;
Arnau, A ;
Hinarejos, JJ ;
de Parga, ALV ;
Hofer, WA ;
Echenique, PM ;
Miranda, R .
PHYSICAL REVIEW LETTERS, 2004, 92 (20) :206101-1
[8]   Structural coherency of graphene on Ir(111) [J].
Coraux, Johann ;
N'Diaye, Alpha T. ;
Busse, Carsten ;
Michely, Thomas .
NANO LETTERS, 2008, 8 (02) :565-570
[9]   Comment on "Periodically Rippled Graphene: Growth and Spatially Resolved Electronic Structure" - Reply [J].
de Parga, A. L. Vazquez ;
Calleja, F. ;
Borca, B. ;
Passeggi, M. C. G., Jr. ;
Hinarejos, J. J. ;
Guinea, F. ;
Miranda, R. .
PHYSICAL REVIEW LETTERS, 2008, 101 (09)
[10]   Atomic beam diffraction from solid surfaces [J].
Farías, D ;
Rieder, KH .
REPORTS ON PROGRESS IN PHYSICS, 1998, 61 (12) :1575-1664