A halide-free route to Groups 12 and 13 organometallic and metalloorganic complexes

被引：35

作者：

Edwards, AJ ^{[1
]}

Fallaize, A ^{[1
]}

Raithby, PR ^{[1
]}

Rennie, MA ^{[1
]}

Steiner, A ^{[1
]}

Verhorevoort, KL ^{[1
]}

Wright, DS ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 01期

关键词：

D O I：

10.1039/dt9960000133

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Nucleophilic substitution of the bis(trimethylsilyl)amido groups of [M{N(SiMe(3))(2)}(2)] (M = Zn or Cd) and [In{N(SiMe(3))(2)}(3)] was found to be a halide-free and homogeneous approach to organometallic and metalloorganic complexes. The breadth of this new synthetic approach is illustrated by the formation of [Cd(SCPh(3))(2)(tmen)] 1 (tmen = Me(2)NCH(2)CH(2)NMe(2)), [(PhC=C)(4)Zn{Li(tmen)}(2)] 2 and [Li(thf)(4)][In(C=CPh)(4)] 3 (thf = tetrahydrofuran) from nucleophilic substitution reactions utilising [M{N(SiMe(3))(2)}(2)] (M = Zn or Cd) and [In{N(SiMe(3))(2)}(3)], the outcome of which is dependent upon the Lewis bases and nucleophiles employed and the metal centres concerned. The crystal structures of complexes 1-3 have been determined.

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页码：133 / 137

页数：5

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