Chemical fixation of carbon dioxide by NaI/PPh3/PhOH

被引：237

作者：

Huang, JW ^{[1
]}

Shi, M ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 68卷 / 17期

关键词：

D O I：

10.1021/jo0348221

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of catalytic amounts of sodium iodide, triphenylphosphine, and phenol, carbon dioxide can efficiently react with epoxides to give the corresponding five-membered cyclic carbonates in high yields. The mechanism of this reaction was disclosed by P-31 NMR spectroscopic data and deuterium labeling experiments.

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收藏

页码：6705 / 6709

页数：5

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