The first example of a doubly orthometallated aryl bis(phosphinite) ligand

被引:12
作者
Bedford, RB [1 ]
Blake, ME
Coles, SJ
Hursthouse, MB
Scully, PN
机构
[1] Univ Exeter, Sch Chem, Exeter EX4 4QD, Devon, England
[2] Univ Southampton, Dept Chem, EPSRC Natl Crystallog Serv, Southampton SO17 1BJ, Hants, England
[3] Univ Dublin Trinity Coll, Dept Chem, Dublin 2, Ireland
关键词
D O I
10.1039/b305136f
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction of 2-methylresorcinolbis(diphenyl) phosphinite with Pd(TFA)(2) gives a dimeric tetranuclear complex which contains two of the ligands, each di-orthopalladated; the X-ray structure of the complex has been determined and its reactivity briefly examined.
引用
收藏
页码:2805 / 2807
页数:3
相关论文
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[21]   Double cyclometalation via carbon-silicon bond cleavage by palladium(II) acetate. X-ray structure of a cationic 1,4-dipalladated benzene ring and selective synthesis of heterobimetallic 1,4-phenylene-bridged platinum(II)-palladium(II) complexes [J].
Steenwinkel, P ;
James, SL ;
Grove, DM ;
Kooijman, H ;
Spek, AL ;
vanKoten, G .
ORGANOMETALLICS, 1997, 16 (04) :513-515