共 33 条
Efficient Synthesis of Panchromatic Dyes for Energy Concentration
被引:73
作者:
Bura, Thomas
[1
]
Retailleau, Pascal
[2
]
Ziessel, Raymond
[1
]
机构:
[1] CNRS, Ecole Europeenne Chim Polymeres & Mat, Lab Chim Mol & Spect Avancees LCOSA, F-67087 Strasbourg 02, France
[2] ICSN CNRS, Cristallochim Lab, Gif Sur Yvette, France
关键词:
dyes/pigments;
energy transfer;
fluorescence;
formylation;
iterative synthesis;
BODIPY DYES;
DISTYRYL-BORADIAZAINDACENES;
EXCITATION-ENERGY;
CHEMISTRY;
ARRAYS;
DENDRIMER;
DEVICES;
D O I:
10.1002/anie.201003206
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Channel your energy: Bodipy dyes were linked covalently by a method involving three key steps, including a carboformylation reaction. All multichromophoric dyes exhibited highly efficient photoinduced energy transfer to the terminal Bodipy modules, which fluoresced at 652 nm with 57 □ % quantum efficiency (see absorption (gray) and emission (orange) spectra of a dye containing five Bodipy units). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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页码:6659 / 6663
页数:5
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