Efficient Synthesis of Panchromatic Dyes for Energy Concentration

被引:73
作者
Bura, Thomas [1 ]
Retailleau, Pascal [2 ]
Ziessel, Raymond [1 ]
机构
[1] CNRS, Ecole Europeenne Chim Polymeres & Mat, Lab Chim Mol & Spect Avancees LCOSA, F-67087 Strasbourg 02, France
[2] ICSN CNRS, Cristallochim Lab, Gif Sur Yvette, France
关键词
dyes/pigments; energy transfer; fluorescence; formylation; iterative synthesis; BODIPY DYES; DISTYRYL-BORADIAZAINDACENES; EXCITATION-ENERGY; CHEMISTRY; ARRAYS; DENDRIMER; DEVICES;
D O I
10.1002/anie.201003206
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Channel your energy: Bodipy dyes were linked covalently by a method involving three key steps, including a carboformylation reaction. All multichromophoric dyes exhibited highly efficient photoinduced energy transfer to the terminal Bodipy modules, which fluoresced at 652 nm with 57 □ % quantum efficiency (see absorption (gray) and emission (orange) spectra of a dye containing five Bodipy units). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:6659 / 6663
页数:5
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