Self-organization of electroactive materials:: A head-to-tail donor-acceptor supramolecular polymer

被引：141

作者：

Fernandez, Gustavo ^{[1
]}

Perez, Emilio M. ^{[1
]}

Sanchez, Luis ^{[1
]}

Martin, Nazario ^{[1
]}

机构：

[1] Fac Ciencias Quim, Dept Quim Organ, Madrid 28040, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 06期

关键词：

pi interactions; fullerenes; host-guest systems; self-assembly; supramolecular polymers;

D O I：

10.1002/anie.200703049

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Fullerenes do the conga! Synthesis and self-recognition of a monomer featuring a specially designed receptor for [60]fullerene are described. The monomer self-assembles in a head-to-tail fashion through π-π interactions, thus forming a linear oligomeric species in solution (see image). The formation of this redox-amphoteric supramolecular polymer represents a new approach to the controlled organization of electroactive materials. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1094 / 1097

页数：4

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