Inorganic nanoporous films from block copolymer thin film

被引：24

作者：

Gong, Yumei ^{[1
]}

Joo, Wonchul ^{[1
]}

Kim, Youngsuk ^{[1
]}

Kim, Jin Kon ^{[1
]}

机构：

[1] Pohang Univ Sci & Technol, Dept Chem Engn, Natl Creat Res Initiat Ctr Block Copolymer Self A, Pohang 790784, Kyunbuk, South Korea

来源：

CHEMISTRY OF MATERIALS | 2008年 / 20卷 / 04期

关键词：

D O I：

10.1021/cm7026256

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A method for preparing inorganic nanoporous films by using the template with polystyrene nanopillars oriented vertically to a substrate was demonstrated. The nanopillar structure was prepared by thermal annealing and subsequent solvent vapor annealing of polystyrene-b-PMMA film followed by removal of the PMMA matrix. The film was annealed under acetone vapor to have vertically oriented cylindrical microdomains of PS block, and the PS nanopillars in the film were removed by thermal decomposition at high-temperature, generating inorganic nanoporous films. Field emission-scanning electron microscopy (FE-SEM) images showed that straight cylindrical pores spanning the entire film thickness were observed for all of the inorganic films. Experimental investigation showed that the inorganic nanoporous films exhibit good thermal and mechanical stabilities, and could be employed for special membranes for the separation at very high temperature.

引用

页码：1203 / 1205

页数：3

共 23 条

[1]

Brandrup J., 1989, Polymer Handbook, V3

[2] Biomimetic approaches for fabricating high-density nanopatterned arrays [J].