Arylation of α-substituted acrylates in ionic liquids catalyzed by a Pd-benzothiazole carbene complex

被引:73
作者
Calò, V [1 ]
Nacci, A [1 ]
Lopez, L [1 ]
Napola, A [1 ]
机构
[1] Univ Bari, Dipartimento Chim, CNR, Ctr MISO, I-70126 Bari, Italy
关键词
beta-aryl ketones; ionic liquids; carbenes; Heck reaction;
D O I
10.1016/S0040-4039(01)00795-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A Pd-catalyst with benzothiazole carbene as ligands allows, in tetrabutylammonium bromide melt as solvent, very fast and efficient reactions of bromoaromatics with 3-hydroxy-2-methylenealkanoates to give beta -arylketones. (C) 2001 Published by Elsevier Science Ltd.
引用
收藏
页码:4701 / 4703
页数:3
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