Efficient Tuning of LUMO Levels of 2,5,8,11-Substituted Perylenediimides via Copper Catalyzed Reactions

被引：74

作者：

Battagliarin, Glauco ^{[1
]}

Zhao, Yanfei ^{[1
]}

Li, Chen ^{[1
]}

Muellen, Klaus ^{[1
]}

机构：

[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 13期

关键词：

SEMICONDUCTORS; DIIMIDE; TRANSISTORS; BISIMIDES; STABILITY; DESIGN; ARENES;

D O I：

10.1021/ol201144w

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Via one-step copper catalyzed procedures it was possible to synthesize 2,5,8,11-tetrabromo, tetrachloro, and tetracyano derivatives of perylenediimides. Characterization of optical and electrochemical properties of these materials proves substantial enhancement of the electron affinity, with a LUMO level as low as -4.4 eV in the case of the tetracyano perylenediimide.

引用

页码：3399 / 3401

页数：3

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