Stationary and mobile phases in capillary electrochromatography (CEC)

被引：22

作者：

Jiskra, J

Claessens, HA

Cramers, CA

机构：

[1] Eindhoven Univ Technol, Dept Polymer Technol, Instrumental Anal Lab, NL-5600 MB Eindhoven, Netherlands

[2] Synthon BV, NL-6503 GN Nijmegen, Netherlands

[3] Eindhoven Univ Technol, Dept Chem & Chem Engn, Instrumental Anal Lab, NL-5600 MB Eindhoven, Netherlands

来源：

JOURNAL OF SEPARATION SCIENCE | 2003年 / 26卷 / 15-16期

关键词：

capillary electrochromatography; capillary liquid chromatography; stationary phases; mobile phases; separation mechanism; applications;

D O I：

10.1002/jssc.200301305

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

This review describes the state of the art of capillary electrochromatography (CEC). Properties of and interactions between stationary and mobile phases applied in CEC are described and discussed; developments in stationary phases, partly also monolithic stationary phases, are reviewed. Special attention is paid to the comparison of the behaviour of stationary and/or mobile phases under CEC versus HPLC conditions with respect to variables such as particle and pore size of the stationary phase, mobile phase composition, and temperature. These issues are discussed throughout the paper. A number of applications in CEC is presented as well.

引用

页码：1305 / 1330

页数：26

共 483 条

[1] Capillary electrochromatographic evaluation of vitamin E-active oil constituents: tocopherols and tocotrienols [J].