Cooperative Bond Activation and Catalytic Reduction of Carbon Dioxide at a Group 13 Metal Center

被引：146

作者：

Abdalla, Joseph A. B. ^{[1
]}

Riddlestone, Ian M. ^{[1
]}

Tirfoin, Remi ^{[1
]}

Aldridge, Simon ^{[1
]}

机构：

[1] Univ Oxford, Dept Chem, Inorgan Chem Lab, Oxford OX1 3QR, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 17期

基金：

英国工程与自然科学研究理事会;

关键词：

beta-diketiminate; bond activation; carbon dioxide; cooperative reactivity; gallium; N-HETEROCYCLIC SILYLENE; FRUSTRATED LEWIS PAIRS; LIGAND COOPERATION; H BOND; CO2; METHANOL; HYDROGENATION; GERMYLENE; CARBENES; ALUMINUM;

D O I：

10.1002/anie.201500570

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A single-component ambiphilic system capable of the cooperative activation of protic, hydridic and apolar H-X bonds across a Group 13 metal/activated beta-diketiminato (Nacnac) ligand framework is reported. The hydride complex derived from the activation of H-2 is shown to be a competent catalyst for the highly selective reduction of CO2 to a methanol derivative. To our knowledge, this process represents the first example of a reduction process of this type catalyzed by a molecular gallium complex.

引用

页码：5098 / 5102

页数：5

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