Exceptional redox and photophysical properties of a triply fused diporphyrin-C60 conjugate:: Novel scaffolds for multicharge storage in molecular scale electronics

被引：116

作者：

Bonifazi, D

Scholl, M

Song, FY

Echegoyen, L ^{[1
]}

Accorsi, G

Armaroli, N

Diederich, F

机构：

[1] Clemson Univ, Dept Chem, Hunter Labs 219, Clemson, SC 29634 USA

[2] Ist Sintesi Organ & Fotoreatt, I-40129 Bologna, Italy

[3] ETH Honggerberg, HCI, Organ Chem Lab, CH-8093 Zurich, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 40期

关键词：

electrochemistry; electron transfer; fullerenes; luminescence; porphyrinoids;

D O I：

10.1002/anie.200352265

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Up to fifteen electrons are reversibly accommodated in a triply fused porphyrin dimer conjugated to two [60]fullerene moieties. Its photophysical properties differ completely from those of the many known porphyrin-fullerene dyads: Photo-excitation of the C60 moieties results in quantitative sensitization of the low-lying (about 1 eV) and very short lived lowest singlet level of the porphyrin sheet (see scheme).

引用

页码：4966 / 4970

页数：5

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[3]

2-Q

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