Highly selective CO2 capture of an agw-type metal-organic framework with inserted amides: experimental and theoretical studies

被引：169

作者：

Duan, Jingui ^{[1
]}

Yang, Zhen ^{[2
]}

Bai, Junfeng ^{[1
]}

Zheng, Baishu ^{[1
]}

Li, Yizhi ^{[1
]}

Li, Shuhua ^{[2
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China

[2] Nanjing Univ, Inst Theoret & Computat Chem, Nanjing 210093, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 25期

关键词：

PRUSSIAN BLUE ANALOGS; CARBON-DIOXIDE CAPTURE; ADSORPTION PROPERTIES; SURFACE-AREAS; SEPARATION; STORAGE; HYDROGEN; GAS; BINDING; MOFS;

D O I：

10.1039/c2cc16231h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An amide-inserted metal-organic framework (NJU-Bai3) presents high storage and high selectivity toward CO2 and combines these two interesting characters which strongly support our expectation that amide groups can significantly enhance the CO2 binding ability and selectivity of MOFs.

引用

收藏

页码：3058 / 3060

页数：3

相关论文

共 53 条

[1] High and Selective CO2 Uptake in a Cobalt Adeninate Metal-Organic Framework Exhibiting Pyrimidine- and Amino-Decorated Pores [J].

An, Jihyun ;

Geib, Steven J. ;

Rosi, Nathaniel L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (01) :38-+

[2] Amine functionalised metal organic frameworks (MOFs) as adsorbents for carbon dioxide [J].

Arstad, Bjornar ;

Fjellvag, Helmer ;

Kongshaug, Kjell Ove ;

Swang, Ole ;

Blom, Richard .

ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2008, 14 (06) :755-762

[3] CO2 absorption in aqueous solutions of alkanolamines:: Mechanistic insight from quantum chemical calculations [J].

Arstad, Bjornar ;

Blom, Richard ;

Swang, Ole .

JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 111 (07) :1222-1228

[4] Storage and separation of CO2 and CH4 in silicalite, C168 schwarzite, and IRMOF-1:: A comparative study from monte carlo simulation [J].

Babarao, Ravichandar ;

Hu, Zhongqiao ;

Jiang, Jianwen ;

Chempath, Shaji ;

Sandler, Stanley I. .

LANGMUIR, 2007, 23 (02) :659-666

[5] Separation of CO2 from CH4 using mixed-ligand metal-organic frameworks [J].

Bae, Youn-Sang ;

Mulfort, Karen L. ;

Frost, Houston ;

Ryan, Patrick ;

Punnathanam, Sudeep ;

Broadbelt, Linda J. ;

Hupp, Joseph T. ;

Snurr, Randall Q. .

LANGMUIR, 2008, 24 (16) :8592-8598

[6] Separation of gas mixtures using Co(II) carborane-based porous coordination polymers [J].

Bae, Youn-Sang ;

Spokoyny, Alexander M. ;

Farha, Omar K. ;

Snurr, Randall Q. ;

Hupp, Joseph T. ;

Mirkin, Chad A. .

CHEMICAL COMMUNICATIONS, 2010, 46 (20) :3478-3480

[7] Synthesis of inorganic fullerene-like molecules [J].

Bai, JF ;

Virovets, AV ;

Scheer, M .

SCIENCE, 2003, 300 (5620) :781-783

[8] Synthesis and characterization of Prussian blue analogues incorporating the edge-bridged octahedral [Zr6BCl12]2+ cluster core [J].

Beauvais, LG ;

Long, JR .

INORGANIC CHEMISTRY, 2006, 45 (01) :236-243

[9] Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites [J].

Britt, David ;

Furukawa, Hiroyasu ;

Wang, Bo ;

Glover, T. Grant ;

Yaghi, Omar M. .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2009, 106 (49) :20637-20640

[10] A route to high surface area, porosity and inclusion of large molecules in crystals [J].

Chae, HK ;

Siberio-Pérez, DY ;

Kim, J ;

Go, Y ;

Eddaoudi, M ;

Matzger, AJ ;

O'Keeffe, M ;

Yaghi, OM .

NATURE, 2004, 427 (6974) :523-527

← 1 2 3 4 5 6 →