Highly selective CO2 capture of an agw-type metal-organic framework with inserted amides: experimental and theoretical studies

被引：169

作者：

Duan, Jingui ^{[1
]}

Yang, Zhen ^{[2
]}

Bai, Junfeng ^{[1
]}

Zheng, Baishu ^{[1
]}

Li, Yizhi ^{[1
]}

Li, Shuhua ^{[2
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China

[2] Nanjing Univ, Inst Theoret & Computat Chem, Nanjing 210093, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 25期

关键词：

PRUSSIAN BLUE ANALOGS; CARBON-DIOXIDE CAPTURE; ADSORPTION PROPERTIES; SURFACE-AREAS; SEPARATION; STORAGE; HYDROGEN; GAS; BINDING; MOFS;

D O I：

10.1039/c2cc16231h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An amide-inserted metal-organic framework (NJU-Bai3) presents high storage and high selectivity toward CO2 and combines these two interesting characters which strongly support our expectation that amide groups can significantly enhance the CO2 binding ability and selectivity of MOFs.

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收藏

页码：3058 / 3060

页数：3

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