4(1H)-quinolinone alkaloids. An efficient synthesis of graveoline by palladium-catalysed reductive N-heterocyclisation.

被引：33

作者：

Annunziata, R

Cenini, S

Palmisano, G

Tollan, S

机构：

[1] DIPARTIMENTO CHIM ORGAN METALLORGAN & ANALIT,I-20133 MILAN,ITALY

[2] CTR CNR,I-20133 MILAN,ITALY

[3] DIPARTIMENTO SCI & TECNOL FARM,I-10125 TURIN,ITALY

来源：

SYNTHETIC COMMUNICATIONS | 1996年 / 26卷 / 03期

关键词：

D O I：

10.1080/00397919608003640

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient synthesis of the 4H-quinolone alkaloid graveoline has been achieved by a route featuring an Pd(II)-catalysed reductive N-heterocyclisation [CO(3 MPa), Pd(TMB)(2), TMPhen, 170 degrees C, 3h] of 2'-nitrochalcone as a key step.

引用

页码：495 / 501

页数：7

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