Efficient immobilization of a cadmium chemosensor in a thin film: Generation of a cadmium sensor prototype

被引:123
作者
Bronson, RT [1 ]
Michaelis, DJ
Lamb, RD
Husseini, GA
Farnsworth, PB
Linford, MR
Izatt, RM
Bradshaw, JS
Savage, PB
机构
[1] Coll So Idaho, Dept Phys Sci, Bratislava 83301, Slovakia
[2] Brigham Young Univ, Dept Chem & Biochem, Provo, UT 84602 USA
关键词
D O I
10.1021/ol050027t
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The development of an ion-selective chemosensor for Cd2+ allows generation of a "real-time" sensor, Immobilization of the chemosensor on quartz was achieved in a simple monolayer and in a thin film using a polymer intermediary. As intended, the thin film contains much more chemosensor than the monolayer and provides measurable responses to aqueous Cd2+ concentrations below 1 mu M. Alkali and alkaline earth ions do not interfere with Cd2+ sensing; Zn2+ and Cu2+ are potential interferents.
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页码:1105 / 1108
页数:4
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