A functional model of galactose oxidase: catalytic oxidation of primary alcohols with a one-electron oxidized copper(II) complex

被引：64

作者：

Saint-Aman, E

Menage, S

Pierre, JL

Defrancq, E

Gellon, G

机构：

[1] Univ Grenoble 1, CNRS, UMR 5630, LEOPR, F-38041 Grenoble 09, France

[2] CEA Grenoble, CB, DBMS, CRCRB, F-38045 Grenoble, France

[3] Univ Grenoble 1, CNRS, UMR 5616, LEDSS, F-38041 Grenoble 09, France

来源：

NEW JOURNAL OF CHEMISTRY | 1998年 / 22卷 / 05期

关键词：

D O I：

10.1039/a801588k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrochemically one-electron oxidized copper(II) complex of N, N'-bis (2-hydroxy-3,5-di-tert-butylbenzyl)-1,2-ethylenediamine catalyses, in the presence of KOH at room temperature, the oxidation of primary alcohols into aldehydes (turnovers > 30); secondary alcohols are not oxidized under the same conditions.

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收藏

页码：393 / 394

页数：2

相关论文

共 13 条

[1] Heteroleptic tripodal complexes of copper(II) .2. Formation of axial phenolate-metal bonds in square-pyramidal complexes [J].

Adams, H ;

Bailey, NA ;

Campbell, IK ;

Fenton, DE ;

He, QY .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (11) :2233-2237

[2] TRIVALENT COPPER AS A PROBABLE INTERMEDIATE IN REACTION CATALYZED BY GALACTOSE OXIDASE [J].

DYRKACZ, GR ;

LIBBY, RD ;

HAMILTON, GA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (02) :626-628

[3] Synthetic models of the inactive copper(II)-tyrosinate and active copper(II)-tyrosyl radical forms of galactose and glyoxal oxidases [J].

Halfen, JA ;

Jazdzewski, BA ;

Mahapatra, S ;

Berreau, LM ;

Wilkinson, EC ;

Que, L ;

Tolman, WB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (35) :8217-8227

[4] Modeling of the chemistry of the active site of galactose oxidase [J].

Halfen, JA ;

Young, VG ;

Tolman, WB .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (15) :1687-1690

[5] Active site models for galactose oxidase. Electronic effect of the thioether group in the novel organic cofactor [J].

Itoh, S ;

Takayama, S ;

Arakawa, R ;

Furuta, A ;

Komatsu, M ;

Ishida, A ;

Takamuku, S ;

Fukuzumi, S .

INORGANIC CHEMISTRY, 1997, 36 (07) :1407-1416

[6] OXIDATIONS OF PRIMARY ALCOHOLS WITH A COPPER(II) COMPLEX AS A POSSIBLE GALACTOSE-OXIDASE MODEL [J].

KITAJIMA, N ;

WHANG, K ;

MOROOKA, Y ;

UCHIDA, A ;

SASADA, Y .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (20) :1504-1505

[7] Synthesis, crystal structure, and magnetic properties of a ferromagnetically coupled difluoro-bridged dinuclear chromium(III) complex with a substituted tetrahydrosalen derivative as ligand [J].

Sanzenbacher, R ;

Bottcher, A ;

Elias, H ;

Huber, M ;

Haase, W ;

Glerup, J ;

Jensen, TB ;

Neuburger, M ;

Zehnder, M ;

Springborg, J ;

Olsen, CE .

INORGANIC CHEMISTRY, 1996, 35 (26) :7493-7499

[8] Phenoxyl-copper(II) complexes: models for the active site of galactose oxidase [J].

Sokolowski, A ;

Leutbecher, H ;

Weyhermuller, T ;

Schnepf, R ;

Both, E ;

Bill, E ;

Hildebrandt, P ;

Wieghardt, K .

JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, 1997, 2 (04) :444-453

[9] COPPER(II) COMPLEXES OF NOVEL TRIPODAL LIGANDS CONTAINING PHENOLATE AND BENZIMIDAZOLE PYRIDINE PENDANTS - SYNTHESIS, STRUCTURE, SPECTRA AND ELECTROCHEMICAL-BEHAVIOR [J].

UMA, R ;

VISWANATHAN, R ;

PALANIANDAVAR, M ;

LAKSHMINARAYANAN, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (08) :1219-1226

[10] Galactose oxidase model complexes: Catalytic reactivities [J].

Wang, YD ;

Stack, TDP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (51) :13097-13098