A functional model of galactose oxidase: catalytic oxidation of primary alcohols with a one-electron oxidized copper(II) complex

被引：64

作者：

Saint-Aman, E

Menage, S

Pierre, JL

Defrancq, E

Gellon, G

机构：

[1] Univ Grenoble 1, CNRS, UMR 5630, LEOPR, F-38041 Grenoble 09, France

[2] CEA Grenoble, CB, DBMS, CRCRB, F-38045 Grenoble, France

[3] Univ Grenoble 1, CNRS, UMR 5616, LEDSS, F-38041 Grenoble 09, France

来源：

NEW JOURNAL OF CHEMISTRY | 1998年 / 22卷 / 05期

关键词：

D O I：

10.1039/a801588k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrochemically one-electron oxidized copper(II) complex of N, N'-bis (2-hydroxy-3,5-di-tert-butylbenzyl)-1,2-ethylenediamine catalyses, in the presence of KOH at room temperature, the oxidation of primary alcohols into aldehydes (turnovers > 30); secondary alcohols are not oxidized under the same conditions.

引用

页码：393 / 394

页数：2

共 13 条

[11]

WHITTAKER JW, 1994, MET IONS BIOL SYST, V30, P315

[12] Synthesis, structure, and properties of a model for galactose oxidase [J].