Analysis of Broadband Dielectric Spectra in a Na+ Mordenite

被引:3
作者
Devautour, S. [1 ]
Schaefer, H. [2 ]
Giuntini, J. C. [1 ]
Henn, F. [1 ]
Zanchetta, J. V. [1 ]
机构
[1] Univ Montpellier 2, Lab Physicochim Mat Condensee, F-34095 Montpellier, France
[2] Univ Leipzig, Fak Phys, D-04103 Leipzig, Germany
关键词
Sodium; Physical Chemistry; Analytical Chemistry; Distribution Function; Coherence;
D O I
10.1007/BF02375713
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The surface properties of a sodic exchanged mordenite has been studied by means of dielectric measurements. The imaginary part of the permittivity is correctly explained by using a model based on the existence of a distribution function of the interaction energies between sodium ions and the zeolitic lattice. Taking into account the sites involved in the mordenite, four elementary distribution functions have been used. The obtained global distribution function has been compared with that resulting from the application of an "ill-posed and inverse method". A satisfactory coherence is observed between both approaches.
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页码:373 / 378
页数:6
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