Direct and highly efficient synthesis of (Z)-allyl iodides from Baylis-Hillman adducts promoted by TMSCl/NaI system

被引：29

作者：

Li, J

Wang, XX

Zhang, YM

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310028, Peoples R China

[2] Zhejiang Normal Univ, Coll Chem & Life Sci, Jinhua 321004, Zhejiang, Peoples R China

[3] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

SYNLETT | 2005年 / 06期

关键词：

Baylis-Hillman adduct; (Z)-allyl iodide; TMSCl/NaI;

D O I：

10.1055/s-2005-863750

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Direct and efficient transformation of Baylis-Hillman adducts into corresponding (Z)-allyl iodides has been achieved by treatment with TMSCI/NaI in THF at room temperature. The readily available reagents, mild conditions together with its generality make this procedure quite attractive.

引用

页码：1039 / 1041

页数：3

共 27 条

[1] NECIC ACID SYNTHONS .4. REGIOSELECTIVITY IN THE REACTIONS OF CHLORO AND IODO DERIVATIVES OF SELECTED 3-HYDROXY-2-METHYLENEALKANOATE ESTERS WITH ETHYL 2-METHYL-3-OXOBUTANOATE [J].