Synthesis and thermal characterization of zirconium titanate pigments

被引:10
作者
Costa, CEF
Crispim, SCL
Lima, SJG
Paskocimas, CA
Longo, E
Fernandes, VJ
Araújo, AS
Santos, IMG
Souza, AG [1 ]
机构
[1] Univ Fed Paraiba, CCEN, Dept Quim, LTM, BR-58059900 Joao Pessoa, Paraiba, Brazil
[2] Univ Fed Paraiba, CT, Dept Engn Mecan, LSR, BR-58059900 Joao Pessoa, Paraiba, Brazil
[3] Univ Fed Sao Carlos, CCT, Dept Quim, LIEC, BR-13565905 Sao Paulo, Brazil
[4] Univ Fed Rio Grande Norte, CCEN, Dept Quim, BR-59072970 Natal, RN, Brazil
关键词
pigment; polymeric precursors; thermal decomposition; zirconium titanate;
D O I
10.1023/B:JTAN.0000027134.28277.83
中图分类号
O414.1 [热力学];
学科分类号
摘要
The objective of this work was to obtain modern pigments based on zirconium titanate doped with nickel and cobalt using polymeric precursor method. Thermal evolution of ZrTiO4 phase was determined. After primary calcination, the material still exhibits two thermal composition events. Calcination was done between 500 and 1000degreesC, to morphological and structural characterization. Surface area decreased exponentially with temperature increase, while crystallite size increased. ZTCo and ZTNi pigments were applied on ceramic tiles and the good quality of the pigment was observed.
引用
收藏
页码:467 / 473
页数:7
相关论文
共 10 条
[1]   Zirconium titanate: from polymeric precursors to bulk ceramics [J].
Bianco, A ;
Paci, M ;
Freer, R .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1998, 18 (09) :1235-1243
[2]   Zirconium titanate microwave dielectrics prepared via polymeric precursor route [J].
Bianco, A ;
Gusmano, G ;
Freer, R ;
Smith, P .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1999, 19 (6-7) :959-963
[3]  
BURGYAN A, 1982, CERAMIC B, V12, P1001
[4]   The electrolytic preparation and physical characterization of ZrTiO4 films [J].
Gheorghies, C .
JOURNAL OF CRYSTAL GROWTH, 2000, 213 (1-2) :112-115
[5]   Thermal study of the ceramic pigments CoxZn(7-x)Sb2O12 [J].
Gouveia, DS ;
Souza, AG ;
de Maurera, MAMA ;
da Costa, CEF ;
Santos, IMG ;
Prasad, S ;
de Lima, JB ;
Paskocimas, CA ;
Longo, E .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2002, 67 (02) :459-464
[6]  
LOPES PE, 2001, ESMALTES PIGMENTOS C
[7]   SYNTHESIS AND CHARACTERIZATION OF V2O5-SIO2-ZRO2 PIGMENTS BY SOL-GEL METHOD [J].
MONROS, G ;
CARDA, J ;
TENA, MA ;
ESCRIBANO, P ;
SALES, M ;
ALARCON, J .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1992, 147 :588-593
[8]  
MONROS G, 1990, BOL SOC ESP CERAM V, V29, P25
[9]  
Pechini M.P, 1967, US Pat. Off., Patent No. [3330697, 3,330,697]
[10]  
SCHEJBAL F, 1996, CERAMICA INFORMACION, V220, P33