Zirconium titanate microwave dielectrics prepared via polymeric precursor route

被引:41
作者
Bianco, A
Gusmano, G
Freer, R
Smith, P
机构
[1] Univ Roma Tor Vergata, Dipartimento Sci & Tecnol Chim, I-00133 Rome, Italy
[2] Univ Manchester, Ctr Mat Sci, Manchester M1 7HS, Lancs, England
[3] UMIST, Manchester M1 7HS, Lancs, England
[4] Univ Birmingham, IRC Mat, Birmingham B15 2TT, W Midlands, England
关键词
powders chemical preparation; microwave dielectric properties; TiO2; ZrO2;
D O I
10.1016/S0955-2219(98)00353-7
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Zirconium titanate based materials are widely used as dielectric resonators in telecommunications. The performance of the devices depends on compositional and microstructural features. The polymeric precursor route enables the preparation of fine zirconium titanate powders at low processing temperatures. ZrTiO4 powders containing different amount of Hf (0.5% and 40 ppm) were prepared and sintered without additives at 1600 degrees C. The resulting materials were single-phase and had densities 96-98% theoretical. The dielectric Q value at 5 GHz was 5640 and the relative permittivity 36. The presence of Hf does not significantly affect the microwave dielectric response. (C) 1999 Elsevier Science Limited. All rights reserved.
引用
收藏
页码:959 / 963
页数:5
相关论文
共 23 条
[1]   Dielectric characterization of sol-gel derived Sn doped ZrTiO4 thin films [J].
Alexander, TP ;
Uhlmann, DR ;
Teowee, G ;
McCarthy, K ;
McCarthy, F ;
Bukowski, TJ .
INTEGRATED FERROELECTRICS, 1997, 17 (1-4) :221-230
[2]   THE MICROSTRUCTURE AND DIELECTRIC-PROPERTIES OF ZR5TI7O24 CERAMICS [J].
AZOUGH, F ;
WRIGHT, A ;
FREER, R .
JOURNAL OF SOLID STATE CHEMISTRY, 1994, 108 (02) :284-290
[3]   The relationship between the microstructure and microwave dielectric properties of zirconium titanate ceramics [J].
Azough, F ;
Freer, R ;
Wang, CL ;
Lorimer, GW .
JOURNAL OF MATERIALS SCIENCE, 1996, 31 (10) :2539-2549
[4]   CAD REPRESENTATION OF THE SYSTEMS ZRO2-MGO-TIO2 AND ZRO2-MGO-YO1.5 [J].
BATEMAN, C ;
NOTIS, M .
PHYSICA B & C, 1988, 150 (1-2) :122-128
[5]   A COMPARISON OF THE INTERPHASE DEVELOPMENT AND MECHANICAL-PROPERTIES OF NICALON AND TYRANNO SIC FIBER-REINFORCED ZRTIO4 MATRIX COMPOSITES [J].
BENDER, BA ;
JESSEN, TL .
JOURNAL OF MATERIALS RESEARCH, 1994, 9 (10) :2670-2676
[6]   Inorganic sol gel synthesis of zirconium titanate fibres [J].
Bhattacharya, AK ;
Hartridge, A ;
Mallick, KK ;
Taylor, D .
JOURNAL OF MATERIALS SCIENCE, 1996, 31 (21) :5583-5586
[7]   Zirconium titanate: from polymeric precursors to bulk ceramics [J].
Bianco, A ;
Paci, M ;
Freer, R .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1998, 18 (09) :1235-1243
[8]   EFFECT OF SN SUBSTITUTION ON CATION ORDERING IN (ZR1-XSNX)TIO4 MICROWAVE DIELECTRIC CERAMICS [J].
CHRISTOFFERSEN, R ;
DAVIES, PK ;
WEI, XH ;
NEGAS, T .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1994, 77 (06) :1441-1450
[9]   Structural-property relations in a reduced and internally biased oxide wafer (RAINBOW) actuator material [J].
Elissalde, C ;
Cross, LE ;
Randall, CA .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1996, 79 (08) :2041-2048
[10]  
Freer R., 1989, BR CERAM P, V42, P225