A new experimental setup for the study of lipid hydration by energy dispersive X-ray diffraction

被引:11
作者
Caracciolo, G
Petruccetti, M
Caminiti, R
机构
[1] Univ Roma La Sapienza, Dipartimento Chim, I-00185 Rome, Italy
[2] Univ Rome, Dipartimento Fis, Ist Nazl Fis Nucl, Sez Roma, I-00185 Rome, Italy
关键词
D O I
10.1016/j.cplett.2005.08.109
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new hydration cell has been constructed that allows to fully hydrate aligned lipid multibilayers as well as to study lipid hydration by using in situ time-resolved energy dispersive X-ray diffraction. The cell has been used to investigate the evolution of the lamellar d-spacing of dioleoylphosphocoline oriented membranes as a function of both relative humidity (RH) and time. The extreme sensitivity of d to RH was shown and two hydration regimes were detected. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:456 / 460
页数:5
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