Nickel-bipyridine catalysed electrosynthesis of ketones from organic halides and carbon monoxide: kinetic and mechanistic investigations

被引：22

作者：

Ocafrain, M ^{[1
]}

Dolhem, E ^{[1
]}

Nedelec, JY ^{[1
]}

Troupel, M ^{[1
]}

机构：

[1] Univ Paris 12, UMR 7582 CNRS, Lab Electrochim Catalyse & Synth Organ, F-94320 Thiais, France

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 571卷 / 01期

关键词：

nickel carbonyl bipyridine complexes; acylnickel complexes; organic halides carbonylation catalysis;

D O I：

10.1016/S0022-328X(98)00851-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactivity of zerovalent nickel-2,2'-bipyridine complexes towards carbon monoxide and organic halides was investigated by electroanalytical methods. The kinetic data obtained allow us to propose two pathways leading to the formation of an acylnickel complex by electroreduction of Nibpy(2+) in the presence of both CO and a halocarbon. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：37 / 42

页数：6

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