Noncovalent ligand strands for transition-metal helicates: The straightforward and stereoselective self-assembly of dinuclear double-stranded helicates using hydrogen bonding

被引：54

作者：

Telfer, SG ^{[1
]}

Sato, T ^{[1
]}

Kuroda, R ^{[1
]}

机构：

[1] JST, ERATO, Kuroda Chiromorphol Project, Meguro Ku, Tokyo 1530041, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 05期

关键词：

enantioselectivity; helical structures; noncovalent interactions; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200352833

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A genuinely supramolecular approach to transition-metal helicates is presented in which eight simple components (four ions and four small molecules) self-assemble to form dinuclear double helicates, where the ligand strands are built up through hydrogen-bonding interactions (see picture). The self-assembly process was found to be highly stereoselective.

引用

页码：581 / 584

页数：4

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