A polyhedral host constructed using a linear template

被引:68
作者
Hamilton, TD [1 ]
Papaefstathiou, GS [1 ]
MacGillivray, LR [1 ]
机构
[1] Univ Iowa, Dept Chem, Iowa City, IA 52242 USA
关键词
D O I
10.1021/ja0278281
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A linear template is used to direct the synthesis of a "head-to-head" tetrapyridine in the solid state, which, in a second step, assembles with a transition-metal-ion to form a polyhedral metal-organic host with a structure that conforms to a trigonal antiprism. The application of the linear template is reminiscent of the synthetic strategy of nature. Copyright © 2002 American Chemical Society.
引用
收藏
页码:11606 / 11607
页数:2
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