Discrete and infinite coordination arrays derived from a template-directed, solid-state, organic synthesis

被引：103

作者：

Hamilton, TD ^{[1
]}

Papaefstathiou, GS ^{[1
]}

MacGillivray, LR ^{[1
]}

机构：

[1] Univ Iowa, Dept Chem, Iowa City, IA 52242 USA

来源：

CRYSTENGCOMM | 2002年 / 4卷

关键词：

D O I：

10.1039/b202169b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A product derived from a template-directed, organic, solid-stage synthesis, rett-tetrakis(2-pyridyl)cyclobutane (2,2'-tpcb), serves as a bis-chelating ligand upon reaction with Cu(NO3)(2).2.5H(2)O and CuSO4.5H(2)O to produce discrete and infinite coordination arrays. [Cu-2(NO3)(4)(mu-2,2'-tpcb)] (1) and [Cu-2(mu(2)-SO4)(2))(mu-2,2'-tpcb)(H2O)(2)](n).9H(2)O (2), respectively.

引用

页码：223 / 226

页数：4

共 22 条

[1]

Anderson S., 1999, TEMPLATED ORGANIC SY, P38, DOI 10.1002/9783527613526.ch01

[2]

[Anonymous], 2015, Acta Crystallogr., V71, P3

[3]

[Anonymous], 1987, BASIC INORGANIC CHEM

[4] STERICALLY RESTRICTIVE METAL-COMPLEXES - THE SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF (1,2-BIS(6-METHYLPYRIDIN-2-YL)ETHANE-N,N')-(MALONATO)PALLADIUM(II) TRIHYDRATE - PROTON NMR BINDING-STUDIES TO CYTOSINE AND GUANINE DERIVATIVES [J].