Pentacoordinate iron complexes as functional models of the distal iron in [FeFe] hydrogenases

被引：52

作者：

Beyler, Maryline ^{[1
]}

Ezzaher, Salah ^{[1
]}

Karnahl, Michael ^{[1
]}

Santoni, Marie-Pierre ^{[1
]}

Lomoth, Reiner ^{[1
]}

Ott, Sascha ^{[1
]}

机构：

[1] Uppsala Univ, Dept Photochem & Mol Sci, Angstrom Labs, S-75120 Uppsala, Sweden

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 42期

基金：

瑞典研究理事会;

关键词：

ACTIVE-SITE; CRYSTAL-STRUCTURE; COORDINATION; CHALLENGES; REDUCTION; CARBONYL;

D O I：

10.1039/c1cc14449a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mononuclear pentacoordinate iron complexes with a free coordination site were prepared as mimics of the distal Fe (Fe(d)) in the active site of [FeFe] hydrogenases. The complexes catalyze the electrochemical reduction of protons at mild overpotential.

引用

页码：11662 / 11664

页数：3

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